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March 2000

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A Guide to online information about:

Metglas®
(Applications of Amorphous Metals)

by


With today's obsession with smaller, faster, lower power, sometimes we need every little bit of help we can get.  One area of power supply design and shielding that has not made it to the main stream until now is the use of Amorphous Metals.

 "This material offers the potential of reducing the core losses of motors and transformers by more than 70%" - Applications of Low Loss Amorphous Metals in Motors and Transformers by L.A. Johnson, E.P. Cornell, D.J. Baiely, S.M. Hegyi; 81 TD 641-0.  A paper recommended and approved by the IEEE Transformers Committee of the IEEE Power Engineering Society for presentation at the IEEE PES 1981 Transmission and Distribution Conference and Exposition.

"Fundamental 60 Hz core loss for the amorphous iron stator was approximately 1W.  The corresponding silicon iron core loss was 5W, and common iron core loss 10W.  This clearly demonstrated that the low reported core loss of amorphous metal can be achieved in a motor." - Test Results on A Low Loss Amorphous Iron Induction Motor by G.M.Rosenberry, P.G.Frischmann, R.E. Tompkins; Manuscript of August 14, 1981.  The rest of the citation was not available in the copy I have.

The most sysinct explanation of exactly what is meant by Amorphous Metals comes from NASA's Microgravity research program office in the paper:

- Containerless Production of Bulk Metallic Glasses (74-49) -

"When a metal or alloy solidifies, it usually divides into many small crystals. The atoms in each of these crystals are arranged in a periodic fashion known as a crystal lattice. Certain metal alloys, however, can be cooled so fast that the atoms do not have time to arrange themselves in a regular fashion but are instead arranged in a more or less random fashion like the atoms in ordinary glass. Such disordered materials are termed amorphous and have very different properties from the same material in a crystalline state. Present techniques for fast cooling of metals on Earth require that the metal be in very thin ribbon form so that heat can be extracted quickly."

Amorphous metallic alloys (metallic glasses) have, in the past, been prepared by (1) splat cooling, (2) roller quenching, and (3) quenching in water. Methods 1 and 2 induce quenching rates on the order of 10^4 to 10^6 ¡C/sec, while method 3 usually results in a quench rate of 10^2 to 10^3 ¡C/sec. It was, therefore, proposed that the elimination of container walls, which can act as nucleation sites for crystalline growth, could allow production of metallic glasses with slower cooling rates (less than 10^2 ¡C/sec). In a reduced gravity environment where such containerless processing is possible, "..the metal can be cooled below its usual melting point so that when freezing does finally take place, the liquid will be so viscous that the atoms in the liquid cannot rearrange themselves into a crystal."  The ultimate result of this process would be an amorphous metal produced in a bulk form.



http://microgravity.nasa.gov/wimg.html

Gravity is such an accepted part of our lives we rarely think about it even though it affects everything we do. Any time we drop or throw something and watch it fall to the ground, we see gravity in action. Although gravity is a universal force, there are times when it is not desirable to conduct scientific research under its full influence. In these cases, scientists perform their experiments in microgravity—a condition in which the effects of gravity are greatly reduced, sometimes described as "weightlessness."

A microgravity environment gives researchers a unique opportunity to study the fundamental states of matter (solids, liquids, and gases) and the forces that affect them. In microgravity, researchers can isolate and study the influence of gravity on physical processes, as well as phenomena that are normally masked by gravity and thus difficult, if not impossible, to study on Earth.


Safety

CUT RESISTANT GLOVES MUST BE WORN AT ALL TIMES WHEN HANDLING METGLAS DT CORES.

The METGLAS transformer core alloy utilized in these cores is cast in extremely thin and sharp ribbons (25 to 50 µm).

Finger marks may cause core corrosion.

Please wear appropriate safety equipment when handling METGLAS DT cores.


http://www.alliedsignal.com/

http://www.electronicmaterials.com/about/amorph/index.htm

http://www.electronicmaterials.com/about/amorph/index.htm

Amorphous Metals is the world's leading producer of amorphous metal ribbon and components used in the production of electrical distribution transformers, high frequency switching power supplies, anti-theft tags, brazing alloys, and solder. Based on technology developed at AlliedSignal's research facilities in Morristown, NJ, the unit began developing amorphous metals in 1970. Amorphous Metals, also known as metallic glass alloys, differ from traditional metals in that they have a non-crystalline structure and possess unique physical and magnetic properties that combine strength and hardness with flexibility and toughness. Key Products: METGLAS®; Amorphous Metal; Glassy Metal; Metallic Glass; Transformer Core Alloys; Distribution Transformer Cores; METGLAS® High Frequency Cores including the Magnaperm®, Microlite®, and Powerlite® product lines; METGLAS® brazing foil; and Specialty Products.

High Frequency Cores —METGLAS® low profile amorphous metal cores improve switched mode power supplies (SMPS) performance and reduce size and weight.

For SMPS/UPS design, high-frequency electronic cores made with METGLAS® amorphous metal alloy consistently out-perform conventional silicon-steel or ferrite cores. The amorphous structure of the METGLAS® alloy provides lower coercivity, making it the easiest of all ferromagnetic materials to magnetize. This allows faster switching in cores for higher frequency operation. All METGLAS® high-frequency cores experience up to 70% lower losses than cores made of any other material. In addition, amorphous cores have higher saturation inductions than conventional cores, requiring less material for the same applications. This is especially important in circuit design, where optimizing space is always a prime concern.

MICROLITE® Toroidal Cores are manufactured with METGLAS® Amorphous Alloy-SA1 ribbon. "Their unique combination of high saturation flux density and low loss make them the first choice for all energy storage applications, while their distributed gap format renders a distinct RFI advantage compared to conventional air gapped cores, enabling the designer to achieve both size and system cost reduction."

METGLAS® Pulse Power Cores - for high voltage, high power application requiring short, narrow pulses at high rep rate.

SATURABLE REACTORS

Saturable reactors utilize the large change between unsaturated and saturated permeabilities of their cores to delay current for a preset period of time. Similarly, once saturated in the forward direction, they act as a diode temporarily blocking current in the reverse direction.  A Mag Amp is a good example of how to use a Saturable Reactor.

http://www.electronicmaterials.com/products/amorph/pulsepow.htm

MAGNETIC SWITCH PROTECTION (MSP)

MSP devices made with METGLAS® cores dramatically enhanced the reliability and overall lifetime of pulse power systems.

By using a saturable reactor in series with either a semiconductor or thyratron switch, the circuit designer can reduce losses in the switch and extend its life. The saturable reactor is designed to hold-off current until the switch becomes fully conductive (see figure, above).

This delay reduces the overlap between current and voltage in the switch, thereby reducing power absorber in the switch. MSP also offers other advantages. Higher di/dt's to the load are safely achieved by waiting for full conductivity in semiconductor switches. The diode-like characteristic of a saturated reactor provides time for switch recovery.

MAGNETIC PULSE COMPRESSION (MPC)

Magnetic pulse compression utilizes reactors in conjunction with capacitors to shape input pulses into narrow output pulses of much higher current (see above figure). MPC, therefore, allows you to use less expensive input switches with lower current ratings. MPC can also extend the lifetime of the input switch. Advanced MPC devices (capable of generating power levels of multi-terawatts in tens of nanoseconds) have been realized utilizing METGLAS® cores.

"INDUCTION LINEAR ACCELERATORS FOR PHYSICS DIAGNOSTICS" shows a real world example.

Compact Pulsed Power Supplies

Lawrence Livermore National Laboratory has developed a non-linear magnetic core model for circuit design and analysis of the Heavy Ion Fusion Projects MOSFET (metal oxide semiconductor field effect transistor) switched modulator...the first stage of development of a compact, modulator module for driving pulsed plasma loads. The module is capable of generating 800 V, 150 ns pulses at a pulse repetition frequency (prf) of 10 kHz continuous operation. Voltages as high as 50 kV, with pulse widths on the order of 200 ns and prfs of >50 kHz, can be achieved by stacking additional modules.

http://www-dsed.llnl.gov/documents/pulser_tech/rcpctta93.html
Schematic diagram of basic MOSFET-switched modulator.

Magnetic Materials - For complete listing of METGLAS® amorphous alloy developed by AlliedSignal.

Advanced Electrical Transformer Cores & Alloys - for utility transmission and distribution (T&D) systems and commercial/industrial applications reduce operating costs and increase energy efficiency.

More than ever, electric utilities and industries today are searching for technologies to reduce their operating costs and improve energy savings throughout their systems. New transmission and distribution (T&D) technologies are now available to help utilities meet these goals.

With a new generation of Metglas® amorphous metal distribution transformers (AMDTs)—with up to 80% lower core loss than conventional transformers—AlliedSignal is helping utilities worldwide achieve their efficiency objectives. When you consider that 10% of all electricity generated by utilities is lost in the transmission and distribution process, the potential savings through reductions in core loss can be significant.

Ultra-efficient transformer cores made with AlliedSignal's METGLAS® amorphous metal alloy make lower core losses possible. Amorphous metal distribution transformers are key to improving utility economics and enhancing energy conservation efforts worldwide.

Brazing/Soldering - for reliable metal joining, METGLAS® foils and preforms offer consistent strength, flexibility, and temperature resistance. Soldering alloys enable uniform and precise joints.


NATIONAL-ARNOLD
MAGNETICS

National-Arnold Magnetics is now a world-class producer of Amorphous C-Core Products.


The Light Engine

Higher power to weight ratios are achieved as a result of the magnetic materials utilized in the design of the LIGHT ENGINE

Neodymium-Iron-Boron magnets have the strongest magnetic field strength [for their weight and size] than any other magnets commercially available. METGLAS® magnetic alloys exhibit high magnetic saturation with extremely low core loss.  Core loss of 2605CO at 60Hz, 1.4 Tesla, is about 0.1 watts per pound, or one fourth the loss of grade M4 electrical steel. This translates into higher interactive magnetic field densities at higher efficiencies compared to that of conventional materials. One other very important point, is that since METGLAS® exhibits very low core losses, the result is "cool running" magnetic cores which keep the Neodymium magnets temperature below their demagnetization point. Many current Rare Earth magnet motors suffer from overheating which causes the magnets to loose their magnetism. It is not so much the switching of the electromagnets that causes the heating, as it is the magnetic fields induced into the cores as a result of interacting with these extremely powerful magnets. It is claimed that some of these Rare Earth magnet motors have achieved power to weight ratios of 5hp per pound, but reliability problems arose because of overheating.


The Naval Research Laboratory's (NRL)Materials Physics Branch  (Code 6340) Non-Linear Physics Group is studying Magneto-elastic spatial/temporal chaos in Metglas® films.  Also, don't miss their 'Chaos' circuits.


RELATIVISTIC KLYSTRON TWO - BEAM ACCELATOR PROTOTYPE
http://tempest.ece.ucdavis.edu/atri/kennedy/kennedy.html
The SNOWTRON injector, a linear induction injector comprised of twelve 100-kV induction cells, will be modified for use as the electron source. Metglas(TM) cores will be used to obtain the required pulse length. The injector will be operated at about 1.2 MV. Approximately 15 Experimental Test Accelerator (ETA) induction cells will be used to accelerate the beam to 2.5 MeV prior to the modulator.


http://www.kgmagnetics.com/
Magnetic Core Selection for Transformers and Inductors, Second Edition
630 Pages, 165 Figures and over 50 Tables.
Author: Colonel Wm. T. McLyman

Core data to include the latest magnetic materials, such as Kool Mu, Metglas, and Ferrite materials.


Army SBIR Award/TOPIC NUMBER: A97-010

TITLE:

Metglas Acoustic Panels for Damping and Modification of Noise

ABSTRACT/BENEFITS:

Noise from machinery and other sources may be controlled passively by high transmission loss panels and damping, or actively using discrete localized sensors and actuators to cancel noise. Effective enclosures for passive noise control are often heavy, especially below 500 Hz, while active noise cancellation systems can be expensive, bulky, and difficult to adapt to different situations. Satcon proposes to develop light weight high transmission loss panels for noise control. Panels will be formed from an array of magnetostrictive Metglas sheets mounted in light weight frames (less than 1 kg/m(2)), with adjacent loops of wire terminating in an adjustable impedance. The Metglas/frame composite panel will act like a dynamic resonator, making its effective mass much greater than its actual mass.  More can be found here.

The paper describes a rationale for the adoption of amorphous metal distribution transformers in a large scale even though it involves a rather drastic change in the production techniques as compared to the presently widely existing practice in the country. The composition, method of manufacture, precautions in manufacture, handling, processing, and so on. of the material and the final product (i.e., the transformer) are briefly described. As the technology is proven and mature in substantial parts of the world, the major policy making agencies in the country have decided that a minimum percentage of new transformers inducted into system should be of this type.


Pulser Technologies

Defense Sciences Engineering Division has unique facilities and capabilities in addressing high voltage and high current fast rise time pulser design and system integration. These pulsers are typically used in charge deposition, imaging, and radar systems at Lawrence Livermore National Laboratory.

Design work involving Avalanche Transistor Pulsers was presented at the 1994 Power Modulator Symposium and demonstrated the reliability of such designs in a small package.

The Fast Pulse Development Team (FPDT), located at the Lawrence Livermore National Laboratory (LLNL), performs work in designing, testing, and evaluating systems in the area of small scale High Speed Pulsed Power, and High Speed Data Acquisition and Diagnostics. FPDT performs DOE and Commercial research and design that is in the national interest.


Theft Prevention - Proprietary METGLAS strips are used in high-accuracy electronic article surveillance (EAS) systems used by retailers for better inventory control and to detect shoplifters.

What is Tagging Systems? Tagging Systems RF Radio frequency systems EM Magnetic systems Loop system Acousto-magnetic systems Systems divide roughly into two types. RF (Radio frequency) and Magnetic.



Designs of High Frequency MagAmp Regulators 
("Coming Soon Online" according to the Amorphous Metals site.)

MAGNETIC AMPLIFIER OUTPUT REGULATORS

Metglas Products has produced a detailed 24-page application guide for the design of high-frequency mag amp regulators using amorphous alloy. This guide provides a complete description of the mag amp design process, a core specification guide, and reference to the key technical literature on mag amp regulators. Mag amp (magnetic amplifier) output regulators are a popular means of regulating more than one output of a switching power supply. They offer precise regulation of each independent output and are efficient, simple, and reliable. Mag amps are especially suitable for outputs with currents of 1A to several tens of amperes, although they are also used at lower currents where tight regulation and efficiency are essential. The advent of Metglas® Amorphous Alloy 2714A made possible the design of mag amps that can operate at higher frequencies than previously possible. Cores made from this alloy exhibit (1) a high squareness ratio, giving rise to low saturated permeability; (2) low coercive force, indicating a small reset current; and (3) low core loss, resulting in a smaller temperature rise.  This combination of magnetic properties enables Metglas® electronic cores to provide superior precision and efficiency in output regulation.

Here are the first couple of pages:

DESIGN OF HIGH-FREQUENCY MAG AMP OUTPUT REGULATORS
USING METGLAS® AMORPHOUS ALLOY 2714A INTRODUCTION

Mag amp (magnetic amplifier) output regulators became quite popular over the past few years as a way of regulating more than one output of a switching power supply. They offer extremely precise regulation of each independent output, and are efficient, simple and very reliable. Mag amps are particularly well suited for outputs with currents of 1 amp to several tens of amps, although they are also used at lower current where tight regulation and efficiency are extremely important.

The advent of Metglas® amorphous alloy 2714A made possible the design of mag amps that can operate at higher frequencies than previously possible. Cores made from this alloy exhibit: (1) a high squareness ratio, giving rise to low saturated permeability; (2) low coercive force, indicating a small reset current and (3) low core loss, resulting in a smaller temperature rise. This combination of outstanding magnetic properties enables Metglas® Electronic Cores to provide unparalleled precision and efficiency in output regulation.

Although linear regulators and independent switched-mode regulators are also used for regulating outputs, they become somewhat limited at higher frequencies and output currents. Linear regulators are limited by their inefficiencies in handling output currents that exceed one or two amperes. At higher currents, heat sinking schemes are required, which increases the size and cost of the power supply.

Independent switched-mode sub-regulators avoid this inefficiency, but usually require a more complex circuitry which is typically more expensive and less reliable than the mag amp approach.

This application note describes the operation of modern mag amp regulators and guides the reader through the design of the saturable reactor and the control circuitry. Appendix A contains a detailed design example of a simple, low-cost mag amp regulator. Appendix B gives the criterion for choosing the output filter inductor, and Appendix C addresses the design of a control circuit using current-mode feedback.

MAG AMP REGULATOR OPERATION

A mag amp controls an output of a switched-mode power supply by modifying the width of the pulse, which appears at the appropriate secondary of the power transformer before the pulse is "averaged" by the output filter. It does this by delaying the leading edge of the pulse in the same manner as a series switch, which is open during the first portion of the pulse and then closed for the rest of the pulse. The switching function is performed by a saturable reactor—an inductor wound on a magnetic core having a very square B-H loop. The function of the mag amp is illustrated in Figure 1.

In this case, a 12-V, 10-A tightly-regulated output accompanies a 5-V, 40-A main output on a forward converter type of switched-mode converter. The error amplifier U1 controls the reset of the saturable reactor between power pulses, and this reset determines the delay which occurs at the leading edge of the following power pulse. Waveform e2 shows the voltage at the output side of the saturable reactor SR, with the voltage during interval (a) being controlled by the amplifier. The delay time, interval (b), ends when its volt-second product equals the volt-second product applied to the reactor during interval (a). The resulting waveform at the input of the averaging inductor
L is shown as e3.

The primary current, L, steps up at the time the core saturates, as a result of the output current commutating from diode CR2 to diode CR1.

To visualize the operation of the feedback loop, assume the output voltage is too high. This causes the positive (+) input of the amplifier to rise, driving the output of the amplifier in the positive direction. This raises the clamping level 
applied at the output side of the saturable reactor (e2), which increases the amount of reset applied to the mag amp. The result is more delay occurs at the leading edge of the pulse, and the output voltage decreases until it reaches the desired value.

Figure 2 illustrates the operation of the saturable reactor in detail. Assume that a 12-V output is desired from a secondary circuit which would normally produce 20 V. To produce the 20-V output, the waveform at e1 is a square wave with a peak voltage of 40 V and a duty ratio of 0.5. Thus, if the saturable reactor were replaced with a jumper wire the output would be 20 V. This is a result of the output filter averaging the voltage at its input.

With the saturable reactor installed and a clamp voltage (Vc) set at -24 V, the applied reset will be 16 V x 5 us, or 80 volt-microseconds. When the positive pulse is applied to the input of the saturable reactor, the reactor behaves as an open switch until the reset volt-microsecond product expires. Since the applied voltage is 40 V, the delay is 2 microseconds. The pulse applied at the input of the filter (e3) is a 40 V pulse with a duration of 5 - 2 = 3 microseconds. The output voltage is the average of this waveform, namely (40 V x 3 us) / (10 us) =12 V.

In addition to regulating, mag amps are often required to provide current limiting of the individual output. In fact, the requirement for the mag amp reactor is the same for current limiting as it is for regulating down to low values of output current, where the output choke (or output inductor) current is discontinuous. In these cases the saturable reactor must withstand the entire volt-second product of the input waveform. Thus, there are two categories of application: 1) regulation only, and 2) shutdown. "Regulation only" means that the minimum output current for good regulation is high enough to assure continuous choke current, and independent current limiting of the mag amp output is not required.



Magnetostrictive Transducers, Actuators, and Sensors are one application of Metglas®.

http://www.iastate.edu/~terfenol/

What is a Magnetostrictive

Magnetostrictive materials transduce or convert magnetic energy to mechanical energy and vice versa. As a magnetostrictive material is magnetized, it strains. That is, it exhibits a change in length per unit length. Conversely, if an external force produces a strain in a magnetostrictive material, the material's magnetic state will change. This bi-directional coupling between the magnetic and mechanical states of a magnetostrictive material provides a transduction capability that is used for both actuation and sensing devices. Magnetostriction is an inherent material property that will not degrade with time.

With the discovery of "giant" magnetostrictive alloys in the 1970s (materials capable of over 1000 m L/L) there is a renewed interest magnetostrictive transducer technologies. Many uses for magnetostrictive actuators, sensors, and dampers have surfaced in the last two decades as more reliable and larger strain and force giant magnetostrictive materials, such as Terfenol-D and Metglas®, have become commercially available (in the mid to late 1980's). Current applications for magnetostrictive devices include ultrasonic cleaners, high force linear motors, positioners for adaptive optics, active vibration or noise control systems, medical and industrial ultrasonics, pumps, and sonar.


http://www.uspto.gov/patft/index.html 
 
 
 
Pat. No. Title
1. 5,815,386 Snubber for zero current switched networks
2. 5,583,734 Surge arrester with overvoltage sensitive grounding switch
3. 5,532,598 Amorphous metal tagging system for underground structures including elongated particles of amorphous metal embedded in nonmagnetic and nonconductive material
4. 5,470,646 Magnetic core and method of manufacturing core
5. RE35,042 Amorphous antipilferage marker
6. 5,240,682 Reinforced corrugated thin metal foil strip useful in a catalytic converter core, a catalytic converter core containing said strip and an electrically heatable catalytic converter containing said core
7. 5,177,961 Upstream collimator for electrically heatable catalytic converter
8. 5,146,744 Electrically heatable catalytic converter insert
9. 5,140,813 Composite catalytic converter
10. 5,140,812 Core for an electrically heatable catalytic converter
11. 5,138,393 Magnetic core
12. 5,133,812 Corrosion resistant cutting tool and method of manufacture
13. 5,091,253 Magnetic cores utilizing metallic glass ribbons and mica paper interlaminar insulation
14. 5,070,694 Structure for electrically heatable catalytic core
15. 5,015,953 Magnetometer for detecting DC magnetic field variations
16. 4,868,565 Shielded cable
17. 4,766,357 Demagnetization compensated magnetostrictive actuator
18. 4,744,838 Method of continuously processing amorphous metal punchings
19. 4,727,360 Frequency-dividing transponder and use thereof in a presence detection system
20. 4,681,251 Method of joining Ni-base heat resisting alloys
21. RE32,428 Amorphous antipilferage marker
22. 4,654,641 Frequency divider with single resonant circuit and use thereof as a transponder in a presence detection system
23. 4,654,275 Storage life of Pb-In-Ag solder foil by Sn addition
24. 4,594,104 Consolidated articles produced from heat treated amorphous bulk parts
25. 4,553,136 Amorphous antipilferage marker
26. 4,448,853 Layered active brazing material and method for producing it
27. 4,392,169 Magnetic shielding spring
28. 4,250,229 Interlayers with amorphous structure for brazing and diffusion bonding

If there is a down side to Amorphous Metals it is their current costs.


Metglas® is a registered trademark of Allied Metglass Products.


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